膜
丙烯腈
材料科学
超亲水性
丙烯酸
化学工程
接触角
共聚物
静电纺丝
高分子化学
聚合物
溶剂
吸附
乳状液
纳米纤维
聚合
复合材料
有机化学
化学
工程类
生物化学
作者
Chong-Jiang Lv,Hui Li,Akram Yasin,Bin Hao,Xiu Yue,Peng-Cheng Ma
出处
期刊:Polymer
[Elsevier]
日期:2022-10-01
卷期号:258: 125292-125292
被引量:3
标识
DOI:10.1016/j.polymer.2022.125292
摘要
Copolymer consisting of acrylonitrile (AN) and acrylic acid (AA) segments with different molar ratios were synthesized via a mixed-solvent precipitation polymerization method. The prepared polymer was then applied to fabricate nanofiber membrane via electrospinning technique. It was found that when the molar ratio of AN/AA was 80/20, the resultant membrane presented outstanding hydrophilicity with a water contact angle of 0° and water adsorption ratio of 17.10. In addition, the breaking force of optimized membrane was increased by more than 60% when comparing with those of pure PAN homopolymer counterpart due to the hydrogen bonding interaction resulting from the carboxyl groups in AA chain segments. The developed membrane possessed fascinating underwater oleophobicity with oil contact angle over 150° and could effectively separate oil/water mixture and oil-in-water emulsion with excellent separation efficiency beyond 95%, ascribing to the hydration layer on the membrane surface and size-sieving effect arising from the multi-scale pore size in the material. The current study provides a novel insight into the fabrication of hydrophilic membrane for oily wastewater treatment for practical applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI