四苯乙烯
化学
配体(生物化学)
聚合物
衍生工具(金融)
高分子化学
半胱氨酸
硫醇
有机化学
聚集诱导发射
荧光
受体
生物化学
酶
经济
物理
金融经济学
量子力学
作者
Jing jing Quan,Qian Wang,Zhao Li,Yun‐Bao Jiang
摘要
We investigated coordination polymers of Ag+ with a cysteine-based thiol ligand designed to contain a tetraphenylethylene AIEgen (L- and D-1). The coordination polymers, forming in a variety of protic and aprotic organic solvents, such as THF, CH3CN and CH3OH, were shown to undergo aggregation in H2O/THF binary solvents at water volume fractions above 50%, where emission was substantially enhanced while the CD profile was reversed, yet the dependence of the CD signal on ee remained S-shaped for the polymers in the aprotic organic solvents THF and CH3CN, in contrast to that in protic solvents CH3OH and C2H5OH.
科研通智能强力驱动
Strongly Powered by AbleSci AI