Detecting nuclear spins in an organosilane monolayer using nitrogen-vacancy centers for analysis of precursor self-assembly on diamond surface

Abstract We demonstrated the correlation spectroscopy of organosilane monolayers using an ensemble of shallow nitrogen-vacancy centers as the quantum sensor. Several types of organosilane monolayers were grown directly on the diamond surface by exposing the surface to a silane precursor vapor. The feasibility of detecting 1 H and 19 F in the monolayer was examined by correlation spectroscopy measurements. The effect of the magnetic dipole–dipole interaction on the peak width was also discussed by comparing the spectrum of the monolayer with that of surface-attached 1 H and that of immersion oil. The results highlight the feasibility of nitrogen-vacancy centers as the spin probe for physicochemical analyses of monolayers grown on the diamond surface.