化学
锗
类金属
歧化
亚稳态
星团(航天器)
卤化物
卤素
甲苯
结晶学
金属
物理化学
无机化学
催化作用
硅
有机化学
程序设计语言
计算机科学
烷基
作者
Tanja Kunz,Victoria L. Graf,Claudio Schrenk,Andreas Schnepf
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2021-09-11
卷期号:60 (20): 15364-15370
被引量:1
标识
DOI:10.1021/acs.inorgchem.1c01985
摘要
The isolation of the germanium mixed halide cluster Ge14Br8-xClx(PEt3)4 (2) by the reaction of a metastable GeIBr solution (toluene/PEt3) with GeCl2·dioxane provides new insights into the complex formation mechanism of metalloid germanium clusters through the disproportionation reaction of GeIX (X = Cl and Br). It is shown that the GeII halide is involved in at least two steps in the build-up reaction of 2. The molecular structure of 2 is presented together with a plausible reaction mechanism leading to the binary cluster Ge14Br8(PEt3)4 and future aspects of these findings.
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