普鲁士蓝
材料科学
纳米颗粒
水溶液
电化学
氧化还原
阴极
离子
钠
光谱学
电导率
化学工程
无机化学
纳米技术
电极
物理化学
化学
有机化学
冶金
工程类
物理
量子力学
作者
Akhil Shettigar,Brindha Moorthy,Vivek Paulraj,Do Kyung Kim,K. Kamala Bharathi
标识
DOI:10.1149/2162-8777/ac0a42
摘要
We report on the electrochemical properties of 20 nm Na2Ni0.33Co0.33[Fe(CN)6] nanoparticles. Na2Ni0.33Co0.33[Fe(CN)6] nanoparticles overcome the poor electronic conductivity and deliver an initial charge capacity of 77 mAh g−1 at 0.1C rate and and 55 mAh g−1 after 320 cycles at 1C rate. At high current rate of 5C, they deliver 35 mAh g−1 and exhibit almost 100% columbic efficiency. The single redox sodium ion chemistry with 3 V makes the material suitable for non-aqueous sodium ion batteries. The redox couple Fe3+/Fe2+ is seen to be electrochemically active during the charge/discharge process, which is confirmed by ex situ X-ray photon spectroscopy.
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