Assessment of the Upper Particle Size Limit for Quantitative Analysis of Aerosols Using Laser-Induced Breakdown Spectroscopy

The laser-induced plasma vaporization of individual silica microspheres in an aerosolized air stream was investigated. The upper size limit for complete particle vaporization corresponds to a silica particle diameter of 2.1 μm for a laser pulse energy of 320 mJ, as determined by the deviation from a linear mass response of the silicon atomic emission signal. Comparison of the measured silica particle sampling rates and those predicted based on Poisson sampling statistics and the overall laser-induced plasma volume suggests that the primary mechanism of particle vaporization is related to direct plasma−particle interactions as opposed to a laser beam−particle interaction. Finally, temporal and spatial plasma evolution is discussed in concert with factors that may influence the vaporization dynamics of individual aerosol particles, such as thermophoretic forces and vapor expulsion.