吸附
煤
微型多孔材料
体积热力学
多孔性
比表面积
解吸
朗缪尔
化学工程
无烟煤
煤层气
煤矿开采
镜质组
介孔材料
材料科学
矿物学
化学
热力学
有机化学
复合材料
催化作用
工程类
物理
作者
Jiaxin Zhao,Hao Xu,Dazhen Tang,Jonathan P. Mathews,Shu Tao
出处
期刊:Fuel
[Elsevier]
日期:2016-11-01
卷期号:183: 420-431
被引量:196
标识
DOI:10.1016/j.fuel.2016.06.076
摘要
Coal has a heterogenous porosity that influences its specific surface area (SSA) and CH4 adsorption and desorption. However, the pore size distribution obtained with N2 adsorption is only reliable at pore sizes >2 nm omitting the important contribution of micropore (<2 nm). Here, 13 coal samples from three series were measured by both the N2 at 77 K and CO2 at 273 K, respectively, to compared the adsorption pore structure characteristics of different coal ranks, seams, and macrolithotypes, which further revealed the influences of mesopore (2–50 nm) and micropore on CH4 adsorption capacity at different pore sizes. The larger micropore total pore volume (TPV) contributes to the larger micropore SSA. As micropores are common and contribute extensively to most of the SSA (>99%) in these coals, a much better relationship exists between the Dubinin-Radushkevich (DR) SSA and CH4 adsorption capacity (Langmuir volume). With the increase of the coal rank, the CH4 adsorption capacity increases continuously and the DR SSA shows a tendency of first decreasing then increasing; at the same coal rank, from the bright to dull coal, the vitrinite content as well as the DR SSA and CH4 adsorption capacity decreases; for the three main coal seams in the Hancheng mine area, the No. 11 coal has the largest DR SSA and CH4 adsorption capacity followed by the No. 3 coal and No. 5 coal. With CO2 adsorption, it is more significant than N2 adsorption to accurately characterize the microscopic structure of coal and understand the gas adsorption mechanism.
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