Electrophilic Amination of “Carbanions” with N,N‐Dialkyl‐O‐arylsulfonylhydroxylamines

Synthesis of tertiary amines from organometallic compounds can be accomplished by electrophilic amination of the “carbanions” R′⊖ with the hydroxylamine derivatives (1) or (2), R=Me or Et. The scope of this reaction has been systematically investigated.