Functional Metal Organic Framework/SiO2 Nanocomposites: From Versatile Synthesis to Advanced Applications

Metal organic frameworks (MOFs), also called porous coordination polymers, have attracted extensive attention as molecular-level organic-inorganic hybrid supramolecular solid materials bridged by metal ions/clusters and organic ligands. Given their advantages, such as their high specific surface area, high porosity, and open active metal sites, MOFs offer great potential for gas storage, adsorption, catalysis, pollute removal, and biomedicine. However, the relatively weak stability and poor mechanical property of most MOFs have limited the practical application of such materials. Recently, the combination of MOFs with inorganic materials has been found to provide a possible strategy to solve such limitations. Silica, which has excellent chemical stability and mechanical properties, shows great advantages in compounding with MOFs to improve their properties and performance. It not only provides structured support for MOF materials but also improves the stability of materials through hydrophobic interaction or covalent bonding. This review summarizes the fabrication strategy, structural characteristics, and applications of MOF/silica composites, focusing on their application in chromatographic column separation, catalysis, biomedicine, and adsorption. The challenges of the application of MOF/SiO2 composites are addressed, and future developments are prospected.