MXene‐mediated Interfacial Growth of 2D‐2D Heterostructured Nanomaterials as Cathodes for Zn‐based Aqueous Batteries

Abstract In this study, we introduce a novel approach for synthesizing two‐dimensional (2D) MXene heterostructures featuring a sandwiched and cross‐linked network structure. This method addresses the common issue of activity degradation in 2D nanomaterials caused by inevitable aggregation. By utilizing the distinct surface characteristics of MXene, we successfully induced the growth of various 2D nanomaterials on MXene substrates. This strategy effectively mitigates self‐stacking defects and augments the exposure of surface areas. In particular, the obtained 2D‐2D MXene@NiCo‐layered double hydroxide (MH−NiCo) heterostructures exhibit enhanced structural stability, improved chemical reversibility, and heightened charge transfer efficiency, outperforming pure NiCo LDH. The aqueous MH−Ni 4 Co 1 //Zn@carbon cloth (MH−Ni 4 Co 1 //Zn@CC) battery demonstrates exceptional performance with a remarkable specific capacity of 0.61 mAh cm −2 , maintaining 96.6 % capacitance after 2300 cycles. Additionally, it achieves an energy density of 1.047 mWh cm −2 and a power density of 32.899 mW cm −2 . This research not only paves the way for new design paradigms in energy‐related nanomaterials but also offers invaluable insights for the application and optimization of 2D‐2D heterostructures in advanced electrochemical devices.