Anode surface engineering of zinc-ion batteries using tellurium nanobelt as a protective layer for enhancing energy storage performance

材料科学 阳极 成核 润湿 功率密度 储能 表面工程 纳米技术 图层(电子) 电镀(地质) 溶解 电化学 冶金 化学工程 复合材料 功率(物理) 工程类 电极 化学 物理 有机化学 物理化学 量子力学 地质学 地球物理学
作者
Soobeom Lee,Yeonjin Je,Boeun Seok,Hyun Tae Kim,Yong‐Ryun Jo,Soong Ju Oh,Byoungyong Im,Dae Guen Kim,Sang‐Soo Chee,Geon−Hyoung An
出处
期刊:Journal of Energy Chemistry [Elsevier BV]
卷期号:92: 113-123 被引量:51
标识
DOI:10.1016/j.jechem.2024.01.019
摘要

Over the years, zinc-ion batteries (ZIBs) have attracted attention as a promising next-generation energy storage technology because of their excellent safety, long cycling performance, eco-friendliness, and high-power density. However, issues, such as the corrosion and dissolution of the Zn anode, limited wettability, and lack of sufficient nucleation sites for Zn plating, have limited their practical application. The introduction of a protective layer comprising of tellurium (Te) nanobelts onto the surface of Zn anode has emerged as a promising approach to overcome these limitations and improve the electrochemical behavior by enhancing the safety and wettability of ZIBs, as well as providing numerous nucleation sites for Zn plating. In the presence of a Te-based protective layer, the energy power density of the surface-engineered Zn anode improved significantly (ranging from 310 to 144 W h kg−1, over a power density range of 270 to 1,800 W kg−1), and the lifespan capability was extended. These results demonstrate that the proposed strategy of employing Te nanobelts as a protective layer holds great promise for enhancing the energy storage performance of ZIBs, making them even more attractive as a viable energy storage solution for the future.
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