Tannic acid-coated cellulose nanocrystal-reinforced transparent multifunctional hydrogels with UV-filtering for wearable flexible sensors

Ionically conductive hydrogels are an ideal alternative material for applications in wearable flexible sensors to monitor human health. However, producing hydrogels with both high sensitivity and excellent versatility is difficult, and their transparency and UV-blocking properties are significantly limited. Here, with mussel- and gecko-inspired biomimicry, all-biomass-based hydrogels (OGTCGs) with self-adhesive, self-healing, transparent, UV-filtering, frost-resistant, environmentally stable, antibacterial, and biocompatible properties were designed and constructed via a simple one-step approach with a water/glycerol system and borax added without any crosslinker using synergistic dynamic covalent and noncovalent chemistry. The transparency of the OGTCG hydrogel reached 81.06 %, while the added tannic acid-coated cellulose nanocrystal (TA@CNC) induced a UV-blocking effect. The OGTCG hydrogel exhibited a high toughness (218.67 kPa) and modulus (100.32 kPa) reinforced by TA@CNC. The OGTCG hydrogel showed good self-healing abilities with an efficiency of over 90 % after 6 h. In a binary solvent system, the OGTCG hydrogel had environmental stability, as illustrated by density functional theory (DFT), greatly broadening its application range. Moreover, it had an electrical conductivity of 2.3 mS cm-1 and a sensitivity of 3.97. Therefore, with its rapid response and real-time monitoring capabilities, the OGTCG hydrogel shows great potential for applications in monitoring human health.