Studies of Structural, Dielectric, and Impedance Spectroscopy of KBT-Modified Sodium Bismuth Titanate Lead-Free Ceramics

[Image: see text] Lead-free ceramic materials produced from bismuth sodium titanate (Na(0.5)Bi(0.5)TiO(3), NBT)–bismuth potassium titanate (K(0.5)Bi(0.5)TiO(3), KBT) have been developed through a solid-state reaction technique. The structural, dielectric, and piezoelectric characteristics of the ceramic materials were analyzed. Based on the XRD investigation, the morphotropic phase boundary (MPB) was determined for the composition (x (%) = 16 and 20). The effects of the KBT phase on the NBT lattice were examined using the charge density distribution. Furthermore, the dielectric properties indicated the presence of a negative dielectric constant (ε(r)′) as a function of frequency between 1 kHz and 2 MHz. Negative permittivity was observed globally in the (1 – x)NBT–xKBT ceramic which reflects the effect of the dielectric resonance. The grain conduction effect is revealed through the complex impedance spectrum in the form of a semicircular arc within the Nyquist plot. In addition, the samples studied revealed a non-Debye relaxation phenomenon. The relaxation time was determined based on the Vogel-Fulcher law for all samples. DC conductivity was carried out on the ceramics material and revealed that the resistance decreases with increasing temperature indicating a negative temperature coefficient of resistance. The AC conductivity as a function of frequency for different temperatures suggests the presence of a thermally activated conduction mechanism. The activation energy has been determined based on the Arrhenius plot of the DC electrical conductivity as well as the relaxation frequency.