Interface Dipole Management of D‐A‐Type Molecules for Efficient Perovskite Solar Cells

Interfacial engineering of perovskite films has been the main strategies in improving the efficiency and stability of perovskite solar cells (PSCs). In this study, three new donor‐acceptor (D‐A)‐type interfacial dipole (DAID) molecules with hole‐transporting and different anchoring units are designed and employed in PSCs. The formation of interface dipoles by the DAID molecules on the perovskite film can efficiently modulate the energy level alignment, improve charge extraction, and reduce non‐radiative recombination. Among the three DAID molecules, TPA‐BAM with amide group exhibits the best chemical and optoelectrical properties, achieving a champion PCE of 25.29% with the enhanced open‐circuit voltage of 1.174 V and fill factor of 84.34%, due to the reduced defect density and improved interfacial hole extraction. Meanwhile, the operational stability of the unencapsulated device has been significantly improved. Our study provides a prospect for rationalized screening of interfacial dipole materials for efficient and stable PSCs.