Nanowires for Solid‐State Lithium Batteries

Abstract A vital approach to accessing high‐safety and high‐energy‐density lithium batteries is to develop solid‐state electrolytes (SSEs) instead of liquid electrolytes. However, lithium‐ion transport and interface stability issues puzzle the construction of solid‐state lithium batteries (SSLBs). Thus, developing fast‐ionic conductors with high electrochemical performances and chemical stability is crucial to SSLBs. Nanowires (NWs) possess high aspect ratios for maintaining carrier transport along the radial direction, thus being extensively employed in SSLBs for the enhancement of ion transport efficiency, mechanical properties, thermostability, flame retardancy, and interface stability between electrodes and electrolytes, consequently boosting the cycle stability and safety of SSLBs. In this work, the advances in NWs for SSLBs, from rational design and synthesis strategies to applications in composite cathodes, anode materials, and SSEs of SSLBs, are systematically reviewed. The key role of NWs in electrodes and the enhancement mechanism of SSE performance by introducing NWs are concluded in detail. Finally, the existing challenges and anticipated prospects for the future development of advanced nanowire‐based SSLBs are summarized and demonstrated. This review aims to provide a comprehensive understanding to facilitate the application of NWs in SSLBs.