过电位
电催化剂
钴
析氧
催化作用
碳化
材料科学
化学工程
纳米复合材料
碳纤维
阳离子聚合
电解
无机化学
氧气
化学
电化学
纳米技术
高分子化学
复合数
复合材料
有机化学
电极
物理化学
扫描电子显微镜
工程类
电解质
作者
Marcin Biegun,Xuecheng Chen,Ewa Mijowska
标识
DOI:10.1002/celc.201800355
摘要
Abstract Electrocatalysts based on cobalt are promising catalytic materials for water electrolysis. In this work, We reported a catalyst composed of cobalt nanoparticles embeded in a carbon lattice through synthesis with a cationic polymer (PEI) and carbonization process at three temperatures (800, 900 and 1000 °C). The material obtained at 1000 °C showed the highest activity towards the oxygen evolution reaction (OER) in an alkaline medium (1 M KOH). Moreover, the OER overpotential required to reach 10 mA cm −2 of 296 mV, was lower than for the commercial RuO 2 catalyst. Further, the material also exhibited very good stability in a long‐term stability test at 10 mA cm −2 .
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