Water-Based Purification of Ultrathin Silver Nanowires toward Transparent Conductive Films with a Transmittance Higher than 99%

Ultrathin silver nanowires (UTAgNWs) are indispensable to achieve transparent conductive films (TCFs) with overall optoelectronic performance exceeding that of the state-of-the-art indium tin oxide films. Impurities in raw UTAgNW products severely impair the optical properties of TCFs. Unfortunately, highly effective and environment-friendly approaches for purification of UTAgNWs are still lacking. Herein, we report the purification of UTAgNWs using deionized water along with a small amount of surfactants as the purifying agent. TCFs coated with the purified UTAgNWs exhibit a light transmittance of 97.9% and a haze of 1.22% at a sheet resistance of 36.3 Ω sq –1 or a light transmittance of 99.8% and a haze of 0.47% at a sheet resistance of 187.3 Ω sq –1 . Both the transmittance and the haze are among the best reported values for AgNW TCFs in the literature. The purification process does not involve any toxic or hazardous chemicals and is both scalable and cost-effective.