吸热过程
吸附
刚果红
奥斯特瓦尔德成熟
朗缪尔吸附模型
化学工程
材料科学
热液循环
碳纤维
氢氧化物
核化学
化学
无机化学
纳米技术
物理化学
复合材料
复合数
工程类
作者
Jia Zeng,Cong Han,Rui Chang,Daqing Zhang
标识
DOI:10.1051/e3sconf/202126902003
摘要
Hierarchical hollow Mg-Al layered double hydroxide microspheres (HHMs) are successfully prepared by hydrothermal treatment in the presence of carbon dots (CDs). Morphology and structure of the as-prepared samples are characterized using XRD, SEM, FT-IR, and TEM techniques. The growth process of HHMs has been investigated in detail, and Ostwald ripening mechanism is suggested for the hierarchical growth of HHMs. Adsorption isotherms and adsorption kinetics of HHMs for congo red (CR) are investigated. Langmuir and Temkin model are more fitted to the experimental data of CR isotherm adsorption. Adsorption kinetic data obeys the pseudo-second-order kinetic model. Moreover, thermodynamic parameters (ΔG o , ΔH o and ΔS o ) show that the CR adsorption onto HHMs is an endothermic and spontaneous process. The as-prepared HHMs could be a potential adsorbent for wastewater treatment containing anion dyes.
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