Breathable, Degradable Piezoresistive Skin Sensor Based on a Sandwich Structure for High‐Performance Pressure Detection

Abstract Wearable intelligent sensor materials have broad application prospects for human health detection and robot kinematics. 3D structure sensors have the advantages of high sensitivity, a wide detection range, and high strength, as is widely reported in existing research. Here, a sandwich structure involving an encapsulation layer, a 3D conductive network, and an encapsulation layer is prepared. Polyaniline acts as an active conductive filler for the 3D conductive network, while silk fibroin and poly (lactic‐co‐glycolic acid) are used to form a network for carrying conductive materials. Additionally, K‐carrageenan is added to encapsulate the 3D conductive network and prepare a high‐performance green skin sensor. The sensor exhibits high sensitivity (2.54 kPa −1 ) and a wide linear detection range (165.3 kPa). In addition, the pressure sensor possesses excellent durability (>2000 cycles) and a fast response time of 160 ms. Moreover, the sensor is compatible and biodegradable and encapsulated by a nontoxic water‐soluble polymer. On this basis, skin sensors for health monitoring systems and intelligent interactive systems are reported, thus enabling future applications in medical detection and human–machine interaction.