聚氨酯
材料科学
罗丹明B
吸附
傅里叶变换红外光谱
介孔材料
亚甲蓝
罗丹明
化学工程
解吸
衰减全反射
核化学
高分子化学
有机化学
复合材料
化学
催化作用
光催化
量子力学
物理
荧光
工程类
作者
Rajan Kumar,Pawan Kumar,Swati Panigrahi,N. Lakshminarasimhan,Raja Shunmugam
摘要
Abstract Here the thermally catalyzed azide‐alkyne click reaction was invoked for synthesis of functional triazole. The formed triazole was invoked to engineer polyurethane as water immiscible material. The synthesized functional triazole and polyurethane were well characterized using spectroscopic techniques—nuclear magnetic resonance (NMR), electrospray ionization mass spectrum (ESI MS), and attenuated total reflectance Fourier transform infrared (ATR‐FTIR) accordingly. The N 2 adsorption–desorption isotherms confirmed the material to be mesoporous in nature with a surface area of 12.89 m 2 /g, pore volume of 0.085 cc/g, and pore radius of 7.14 nm. The characterized triazole material can be crucial with properties related to antifungal responses and UV absorption. The polyurethane material showed adsorption of amphiphilic dye—rhodamine (RH B) and methylene blue (MB). It was selective to release of rhodamine B (RH B) quite efficiently. The recycling of polyurethane reported up to cycle four revealed efficient adsorption‐release.
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