钙钛矿(结构)
密度泛函理论
材料科学
卤化物
空位缺陷
带隙
太阳能电池
光催化
瓶颈
离子
光电子学
计算化学
化学物理
化学
无机化学
结晶学
计算机科学
生物化学
有机化学
嵌入式系统
催化作用
作者
Xinyu Ye,Anmin Liu,Liguo Gao,Chu Zhang,Lijing Yan,Shizheng Wen,Tingli Ma
出处
期刊:EcoMat
[Wiley]
日期:2022-11-02
卷期号:5 (3)
被引量:5
摘要
Abstract The toxicity of lead ions in halide perovskite absorbing materials is the main bottleneck for practical application. To replace the traditional lead halide perovskites by environmental friendly double perovskite, computational tools based on density functional theory were employed to predict the intrinsic properties of potential double perovskites to efficiently and rapidly find more double perovskites with properties suitable for optoelectronic applications. Screening homovalent alternatives for B and X‐site ions in vacancy‐ordered double perovskite Cs 2 BX 6 for solar cell applications and photocatalyst was done using Perdew–Burke–Ernzerhof and Heyd–Scuseria–Ernzerhof functional with spin‐orbit coupling. Three empirical factors and formation enthalpy were used to evaluate the stability of 30 materials at different temperatures. Finally, the Cs‐based vacancy‐ordered double perovskites with suitable bandgap for optoelectronic applications can thus be obtained. Using computational techniques, this study can also provide theoretical guidance for the rational design of possible double perovskite materials with improved photocatalytic characteristics. image
科研通智能强力驱动
Strongly Powered by AbleSci AI