Effect of Superabsorbent Polymers on the Self-Healing Properties of Pre-Damaged Concrete

Cracks in concrete structures reduce bearing capacity, durability, and safety. This paper reveals the effect of superabsorbent polymers (SAP) on the self-healing property of pre-damaged concrete based on mechanical properties tests, mercury intrusion porosimetry, scanning electron microscopy, and energy dispersive spectrometer. The experimental results show that SAP reduces the mechanical properties of the SAP-modified concrete under the same W/C ratio, but a small amount of SAP can improve the later strength under the 0.35 W/C ratio. The addition of SAP increased the volume of small capillary pores (<20 μm) and large capillary pores (>100 μm) and significantly reduced the former with an increase in age. The SEM-EDS analysis indicates that the water released by SAP promotes the formation of C-S-H gel. AFt in the cracks is the main reason for self-healing, and the addition of CO2 to produce calcium carbonate is another one. Furthermore, this study finds that SAP-modified concrete has the best self-healing effect and the densest structure when the W/C ratio is 0.35 and the SAP content is 0.25%. The self-healing performance makes the SAP-modified concrete have broad application prospects.