Potential of granular complexes of lime and montmorillonite for stabilizing soil cadmium and the underlying mechanisms

Cadmium (Cd) contaminated soils were widely remediated by alkaline materials in powder, while the effects of granular materials are still unknown. This study was conducted to prepare granular materials based on hydrated lime and montmorillonite with ratios of 1:1, 1:2, and 1:3 (LM1, LM2, and LM3); their effects and mechanisms on stabilizing Cd in hydroponic, pot, and field conditions were further explored. The results showed that powdery materials caused intense pH elevations within 30-60 min and dissolved-Cd reductions within 8-100 min. However, granular materials significantly delayed these effects; the highest solution pH and lowest dissolved-Cd occurred after 250 min. The LM1 granules induced a much higher reduction of dissolved-Cd (99.8%) than that in the LM2 (53.6%) and LM3 granules (14.3%) due to the generation of more cadmium carbonate precipitates. Additionally, the soil pH gradually decreased after an intense elevation induced by powdery materials, but the LM1 granules maintained the soil pH at approximately 7.0, resulting in a lower level of CaCl2-extractable Cd (0.03 mg kg-1) than the LM1 powder (0.22 mg kg-1) after 30 d of cultivation. Similar to lime powder, a small spatial variation (Std. of 3.45) of DGT (diffusive gradient in thin films) extractable Cd in soil profile was observed in the LM1 granules, revealing a homogeneous stabilization effect induced by the LM1 granules. Accordingly, the LM1 granules induced a higher reduction in brown rice Cd (50.9%) than that in the LM1 powders (35.1%). Thus, the granular material of hydrated lime and montmorillonite (1:1) h the potential to replace lime powder in the remediation of Cd-contaminated field.