Engineering fast diffusion channels in metal Sulfide/Selenide heterostructures via confinement effect for high-performance sodium storage

Structural modulation plays a pivotal role in enhancing the energy storage properties of electrochemical hybrids by adjusting their interfacial and electronic characteristics. Nevertheless, facile and effective strategies for tuning the structural properties of these hybrids at the nanoscale remain scarce. In this study, we propose a novel in-situ electrochemically self-driven strategy for embedding FeSe/FeS heterostructures with rich phase boundaries concurrently encapsulated into one-dimensional porous N, S-doped carbon tubes with inner void (FeSe/FeS@SNC). This approach facilitates the creation of heterogeneous interface phases via a simple electrochemical conversion from FeS0.75Se0.25. Notably, the resultant unique one-dimensional porous structure with inner void, along with a highly conductive N/S-co-doped carbon matrix, promotes charge transfer and reinforces structural stability. in-situ/ex-situ microscopic and spectroscopic characterizations, supported by theoretical simulations, validate that FeSe/FeS heterostructures offer rapid electron transport pathways, while the abundant heterojunctions with strong electric fields facilitate ion migration and Na adsorption. As an anode in sodium-ion batteries, the FeSe/FeS@SNC electrdoe exhibits exceptional rate capability (347 mAh/g at 10 A/g) and stable cycling performance (91% capacity retention after 12000 cycles).