Exploring the A -V-Sb landscape beyond AV3Sb5 : A case study on the

Kagome compounds have garnered attention in the past few years for their intriguing magnetic properties arising from spin frustration dictated by the geometry of the Kagome sublattice. In this paper, we highlight the success of the unconventional hydride route for the fast and easy synthesis of the Kagome compound $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$. High-temperature in situ powder x-ray diffraction (PXRD) studies proved to be useful in hinting at the existence of $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$, identifying its synthesis conditions, and understanding the reaction mechanism. The crystal structure for $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ was determined from high-resolution PXRD data. The compound has a layered structure $[R\overline{3}m,\phantom{\rule{0.16em}{0ex}}a=5.5318$(9)$\phantom{\rule{0.16em}{0ex}}\mathrm{\AA{}}, c=34.23$(3)$\phantom{\rule{0.16em}{0ex}}\mathrm{\AA{}}, V=907.0$(8)$\phantom{\rule{0.16em}{0ex}}{\mathrm{\AA{}}}^{3}, Z=3$ at room temperature] and features a Kagome bilayer of V atoms. $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ is isostructural to the previously reported $\mathrm{Rb}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ and $\mathrm{Cs}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ compounds. $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ is thermally stable in vacuum up to 1173 K, as evident from the high-temperature in situ PXRD and differential scanning calorimetric analysis. Investigation of magnetic properties for $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ between 2 and 300 K reveals temperature-independent paramagnetism and an absence of superconductivity, like the Rb and Cs analogs. Furthermore, we compare the magnetic properties of $\mathrm{K}{\mathrm{V}}_{3}{\mathrm{Sb}}_{5}$, another ternary Kagome compound, synthesized via two different methods: the hydride route and the traditional route from elements. Low-temperature transport property measurements of $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ indicate metallic behavior and an intrinsically low thermal conductivity of $1.0\phantom{\rule{0.16em}{0ex}}\mathrm{W}\phantom{\rule{0.16em}{0ex}}{\mathrm{K}}^{\ensuremath{-}1}\phantom{\rule{0.16em}{0ex}}{\mathrm{m}}^{\ensuremath{-}1}$ at 300 K. The layered structure of $\mathrm{K}{\mathrm{V}}_{6}{\mathrm{Sb}}_{6}$ makes it an attractive candidate for deintercalation and doping studies to tune both magnetic and transport properties, laying a foundation for further studies.