石墨烯
电化学
钒
材料科学
水溶液
复合数
氧化钒
化学工程
阴极
氧化物
离子
热液循环
无机化学
电极
水热合成
纳米技术
化学
冶金
复合材料
有机化学
物理化学
工程类
作者
Yanzhi Fan,Xiaomeng Yu,Ziyi Feng,Mingjie Hu,Yifu Zhang
出处
期刊:Molecules
[MDPI AG]
日期:2022-08-24
卷期号:27 (17): 5387-5387
被引量:5
标识
DOI:10.3390/molecules27175387
摘要
Layered vanadium-based materials are considered to be great potential electrode materials for aqueous Zn-ion batteries (AZIBs). The improvement of the electrochemical properties of vanadium-based materials is a hot research topic but still a challenge. Herein, a composite of Zn-ion pre-intercalated V2O5·nH2O combined with reduced graphene oxide (ZnVOH/rGO) is synthesized by a facile hydrothermal method and it shows improved Zn-ion storage. ZnVOH/rGO delivers a capacity of 325 mAh·g-1 at 0.1 A·g-1, and this value can still reach 210 mAh·g-1 after 100 cycles. Additionally, it exhibits 196 mAh·g-1 and keeps 161 mAh·g-1 after 1200 cycles at 4 A·g-1. The achieved performances are much higher than that of ZnVOH and VOH. All results reveal that Zn2+ as "pillars" expands the interlayer distance of VOH and facilitates the fast kinetics, and rGO improves the electron flow. They both stabilize the structure and enhance efficient Zn2+ migration. All findings demonstrate ZnVOH/rGO's potential as a perspective cathode material for AZIBs.
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