材料科学
纳米孔
纳米结构
膜
聚合
纳米技术
薄脆饼
锐钛矿
半导体
化学工程
聚合物
催化作用
化学
复合材料
光催化
有机化学
工程类
生物化学
光电子学
作者
Brinda B. Lakshmi,Peter K. Dorhout,Charles R. Martin
摘要
The template method for preparing nanostructures entails synthesis of the desired material within the pores of a nanoporous membrane or other solid. A nanofibril or tubule of the desired material is obtained within each pore. Methods used previously to deposit materials within the pores of such membranes include electrochemical and electroless deposition and in situ polymerization. This paper describes the first use of sol−gel chemistry to prepare semiconductor nanofibrils and tubules within the pores of an alumina template membrane. TiO2, WO3, and ZnO nanostructures have been prepared. TiO2 nanofibrils with diameters of 22 nm were found to be single crystals of anatase with the c-axis oriented along the fibril axis. Bundles of these fibrils were also found to be single crystalline, suggesting that the indiviual fibrils are arranged in a highly organized fashion within the bundle. Finally, 200 nm diameter TiO2 fibrils were used as photocatalysts for the decomposition of salicylic acid.
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