催化作用
分解水
纳米晶
过电位
材料科学
极限抗拉强度
成核
化学工程
水溶液
析氧
纳米技术
氧化物
硼氢化钠
化学
复合材料
冶金
物理化学
有机化学
光催化
电极
工程类
生物化学
电化学
作者
Rongchao Li,Jingjun Liu,Mingyue Xiao,Yanhui Sun,Feng Liu,Jun Gan,Shixin Gao
出处
期刊:Small
[Wiley]
日期:2024-03-26
卷期号:20 (33)
被引量:6
标识
DOI:10.1002/smll.202400095
摘要
Rare earth microalloying nanocrystals have gotten widespread attention due to their unprecedented performances with customization-defected nanostructures, divided energy bands, and ensembled surface chemistry, regarded as a class of ideal electrocatalysts for oxygen evolution reaction (OER). Herein, a lanthanide microalloying strategy is proposed to fabricate strain wave-featured LaRuIr nanocrystals with oxide skin through a rapid crystal nucleation, using thermally assisted sodium borohydride reduction in aqueous solution at 60 °C. The atomic strain waves with alternating compressive and tensile strains, resulting from La-stabilized edge dislocations in form of Cottrell atmospheres. In 0.5 m H
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