Extraction and characterization of fulvic acid from corn straw compost by alkali solution acid precipitation

堆肥 稻草 化学 萃取(化学) 碱金属 降水 傅里叶变换红外光谱 农学 核化学 无机化学 有机化学 生物 化学工程 工程类 物理 气象学
作者
Meisheng Chi,Zhigang Wang,Weihui Xu,Ruixing Hou
出处
期刊:Industrial Crops and Products [Elsevier BV]
卷期号:198: 116678-116678 被引量:12
标识
DOI:10.1016/j.indcrop.2023.116678
摘要

The effective utilization of corn straw is a challenge. Extracting fulvic acid from corn straw compost improves the utilization rate of corn straw, reduces the use of chemical fertilizers, and supports sustainable agricultural development. By the response surface, the best alkali solution acid precipitation extraction conditions were obtained, which involved a KOH concentration of 9.67%, a reaction temperature of 100.32 °C, a reaction time of 9.91 h. Through the Fourier transform infrared spectroscopy (FTIR), it found that BFA contained more oxygen-containing functional groups than MFA, such as those in aliphatic, hydroxyl, ketone and carbonyl groups. Compared to the MFA, the BFA included more types of hydrogen and showed a looser superficial structure. The average molecular model of BFA was constructed with the formula C17H16O7 (M=332). BFA has a lower molecular weight than MFA, which should ensure that BFA is readily absorbed and used by crops. BFA promoted the growth of rice seeds effectively, and the optimal BFA concentration for seed germination was 0.4%. In this study, corn straw composting was used as the main object. The molecular structure of BFA extracted from corn straw compost was established by the alkali solution acid precipitation method. It confirmed that BFA could replace MFA as a biorenewable, environmentally friendly agricultural product.
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