材料科学
热液循环
电化学
阳极
退火(玻璃)
介孔材料
化学工程
氧化物
金属
磁场
纳米技术
储能
作者
Yiyong Wei,Lin Ying,Xiaohang Ma,Lina Zhou,Zhenfa Zi,Jianming Dai
标识
DOI:10.1016/j.jallcom.2022.166774
摘要
A magnetic field induced hydrothermal method is applied to synthesize precursors, followed by annealing to prepare mesoporous MnO microchains. Different morphologies of the ultimate products can be dominated by changing the magnetic field strength to acquire good electrochemical performances. The initial high reversible capacity of MnO microchains is 948 mAh g -1 . After 250 cycles, the reversible capacity retains about 769 mAh g -1 at 2 C, even after 2000 cycles, the reversible capacity maintains around 198 mAh g -1 at 8 C. The superb electrochemical properties could originate from the mesoporosity of aggregated nanoparticles of the MnO 1D-microchain structure induced by applied magnetic field of 8 T, which is beneficial for the fast transport of Li + and electron, and can adapt to the dramatic volume change during the Li + deintercalation. • MnO microchains are prepared by magnetic-field-induced hydrothermal method followed by calcinating. • MnO microchains show superb stable cyclability and high rate capability. • This paper offers a facile method to prepare other metal oxide anode materials for LIBs.
科研通智能强力驱动
Strongly Powered by AbleSci AI