假电容
阳极
材料科学
纳米复合材料
化学工程
电化学
电流密度
介孔材料
纳米颗粒
碳纤维
兴奋剂
法拉第效率
离子
电极
纳米技术
超级电容器
复合材料
光电子学
化学
复合数
有机化学
催化作用
工程类
物理
物理化学
量子力学
作者
Limin Zhu,Zehua Wang,Lei Wang,Lingling Xie,Jingjing Li,Xiaoyu Cao
标识
DOI:10.1016/j.cej.2019.01.191
摘要
ZnSe is regarded as a promising anode material for reversible Li-ion batteries because of its high theoretical capacity. Herein, we report a facile chemical precipitation method to controllably synthesize ZIF-8 nanocubes and then select them as sacrificial templates to prepare ZnSe nanoparticles embedded N-doped carbon nanocubes. The as-obtained ZnSe/carbon nanocomposite at 600 °C demonstrates a high initial discharge capacity of 1170.8 mAh g−1 with the initial columbic efficiency of 68.8% at the current density of 0.1 A g−1 in the voltage range of 0.01–3 V. In addition, it displays a reversible capacity of 1166.6 mAh g−1 after 500 cycles at the current density of 0.5 A g−1, indicating the excellent cyclic stability for the designed composites. The enhanced electrochemical performance can be ascribed to its high specific surface area (493.45 m2 g−1) and unique mesoporous structure, which provides efficient Li+ transport channels and additional storage sites. Furthermore, the existence of faradaic pseudocapacitance in ZnSe/carbon nanocomposites also affords additional capacity and contributes to the increased capacity with respect to charge/discharge cycle number.
科研通智能强力驱动
Strongly Powered by AbleSci AI