石墨氮化碳
材料科学
制氢
氢
X射线光电子能谱
介电谱
分解水
化学工程
傅里叶变换红外光谱
电化学
化学
催化作用
光催化
物理化学
有机化学
工程类
电极
作者
Wenliang Li,Guodong Liu,Nan Si,Dong Liu,Fusheng Wen
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2020-11-24
卷期号:3 (12): 12188-12197
被引量:25
标识
DOI:10.1021/acsanm.0c02667
摘要
The photocatalytic water-splitting hydrogen evolution technology has the potential to relieve energy crisis and enhance the hydrogen generation efficiency of the catalyst. Herein, a kind of 3DOM-CN composite, which is composed of a three-dimensional ordered macroporous material based on g-C3N4, was synthesized through a colloidal template crystal method. After it was doped with Cl– and modified by carbon quantum dots (CQDs), the as-prepared xCQDs/Cl/3DOM-CN composite showed an evident hydrogen generation ability enhancement irradiated by visible light. The structures, composition, and optical and electrochemical properties of the prepared photocatalysts were comprehensively obtained by transmission electron microscopy (TEM), scanning electron microscopy, high-resolution-TEM, X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, UV–vis, electrochemical impedance spectroscopy, photocurrent, Mott–Schottky, and photoluminescence. The highest hydrogen evolution efficiency under visible-light irradiation was achieved by the 1%CQDs/Cl/3DOM-CN composite with a hydrogen generation rate of 8.12 mmol g–1 h–1, which was nearly five times that of the 3DOM-CN. The photocatalyst exhibited an outstanding stability and reusability after four cycles. Eventually, the mechanism in the process of catalytic hydrogen production was briefly discussed. The synergy of the multiple functions of the CQDs/Cl/3DOM-CN composite offered a technique for enhancing the activity of the photocatalysts in the photocatalytic water-splitting process.
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