结晶学
化学
过渡金属
氧原子
氧气
无机化学
催化作用
分子
有机化学
作者
Álvaro Mayoral,Qing Zhang,Yi Zhou,Pengyu Chen,Yanhang Ma,Taro Monji,Pit Losch,Wolfgang Schmidt,Ferdi Schüth,Hajime Hirao,Jihong Yu,Osamu Terasaki
标识
DOI:10.1002/anie.202011447
摘要
The location and identification of all framework atoms in zeolites, including oxygen bridges, extra-framework cations, and isomorphous substitution of Si, are reported by A. Mayoral, O. Terasaki et al. in their Research Article on page 19510. The structures of two important zeolites, Na-LTA and Fe-MFI, were studied by using two complementary electron detectors in an aberration-corrected electron microscope. It is the first direct observation of single transition metal atoms (Fe), which were found to be unevenly substituting the Si at the atomic level in the MFI framework. The location and identification of all framework atoms in zeolites, including oxygen bridges, extra-framework cations, and isomorphous substitution of Si, are reported by A. Mayoral, O. Terasaki et al. in their Research Article on page 19510. The structures of two important zeolites, Na-LTA and Fe-MFI, were studied by using two complementary electron detectors in an aberration-corrected electron microscope. It is the first direct observation of single transition metal atoms (Fe), which were found to be unevenly substituting the Si at the atomic level in the MFI framework. Zeolites Electrode Materials Porous Organic Polymers
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