合成子
超分子化学
纳米技术
超分子手性
化学
组合化学
有机化学
分子
手性(物理)
材料科学
立体化学
物理
对称性破坏
Nambu–Jona Lasinio模型
手征对称破缺
量子力学
作者
Giovanni Preda,Andrea Nitti,Dario Pasini
出处
期刊:ChemistryOpen
[Wiley]
日期:2020-06-01
卷期号:9 (6): 719-727
被引量:22
标识
DOI:10.1002/open.202000077
摘要
Abstract Triptycenes are an intriguing class of organic molecules with several unusual characteristics, such as a propeller‐like shape, saddle‐like cavities around a symmetrical scaffold, a rigid π‐framework. They have been extensively studied and proposed as key synthons for a variety of applications in supramolecular chemistry and materials science. When decorated with an appropriate substitution pattern, triptycenes can be chiral, and, similarly to other popular chiral π‐extended synthons, can express chirality robustly, efficiently, and with relevance to chiroptical spectroscopies. This minireview highlights and encompasses recent advances in the synthesis of chiral triptycenes and in their introduction as molecular scaffolds for the assembly of functional supramolecular materials.
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