Highly Stable and Ultrahigh‐Rate Li Metal Anode Enabled by Fluorinated Carbon Fibers

Abstract The advanced energy storage of an Li metal substituted for graphite anode can provide a significant enhancement in a battery's energy density. Nevertheless, the practical implementation of metallic Li has seriously been fettered by the notorious Li dendrite growth and the huge volumetric variation of Li metal inducing poor cycling performance and safety concerns. In this regard, constructing a robust SEI layer combined with a 3D host to stabilize the Li metal is strongly in demand. Herein, a highly stable hosted Li with an LiF dominated SEI has successfully been achieved through metal‐free fluorinated carbon fibers (FCF) with strong lithiophilicity. The metal‐free design is cost‐effective and can retain the energy density of the Li metal, minimizing the unnecessary energy sacrifice from the extra high gravimetric density lithiophilic sites. The FCF hosted Li delivers a promoted high Coulombic efficiency, homogeneous Li deposition, and ultrahigh rate stable cycling over 1000 cycles at 20 mA cm −2 with a much lower voltage polarization (≈220 mV). Moreover, half cells coupled with LiNi 0.8 Co 0.1 Mn 0.1 O 2 , sulfur or even thick LiCoO 2 cathode demonstrate superior rate performances and enhanced cycling stability even under a lean electrolyte. This work proves the feasibility of FCF hosted Li for practical usage and provides a novel approach toward cost‐effective and high performance lithium metal batteries.