Mercury(编程语言)
硫代酰胺
选择性
水溶液中的金属离子
荧光
光化学
硫黄
污染物
环境化学
镉
金属
分析物
化学
离子
激发态
人类健康
无机化学
材料科学
有机化学
催化作用
物理化学
核物理学
程序设计语言
物理
环境卫生
医学
量子力学
计算机科学
作者
Samjhana Maharjan,Young Ho Yun,Veronica A. Okello,Gary P. Wiederrecht,David J. Gosztola,Anoklase Jean-Luc Ayitou
标识
DOI:10.1016/j.jphotochem.2021.113648
摘要
As Mother Nature is experiencing catastrophic environmental pollutions from both natural sources and anthropogenic activities, many scientists have been working around the clock to develop environmentally benign and cost-effective, yet sensitive, detection techniques for pollutants, especially heavy metal species (e.g. lead, cadmium, mercury, among others) that are deleterious to human health. Herein, we report a novel sulfur-containing small organic dye/sensor naphthoquinodimethyl-bis-thioamide (QDM), which was found to be particularly selective toward mercury ion (Hg2+). Using a combination of UV–vis absorption, photoluminescence, and time-resolved pump–probe techniques, we established that QDM and Hg2+ can form stable complex(es) due to the strong affinity of sulfur toward mercury. In this investigation, while a higher ratio of QDM:Hg2+ was necessary to fully quench the fluorescence emission of QDM, only 1 equiv of the Hg2+ ion was necessary to observe the sensing effect on the excited state photo-behavior(s) of QDM. The present results highlight a synergy between molecular sensors’ selectivity/sensitivity and sensor-analytes dynamics.
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