增塑剂
材料科学
玻璃化转变
流变学
复合材料
聚合物
动态力学分析
悬挂(拓扑)
邻苯二甲酸盐
同伦
数学
纯数学
作者
I. P. Trifonova,J.A. Rodicheva,Anna Sheveleva,V. A. Burmistrov,О. И. Койфман
标识
DOI:10.2298/jsc210817093t
摘要
Flotator Oxal, a mixture of dioxane ethers and alcohols, was studied as a plasticizer for suspension PVC in comparison with the well-known dibutyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DOP). The rheological parameters and gelation ability of the plasticizers were determined, and the values of the storage modulus and tangent of mechanical loss angle in the glassy and rubbery states were measured by the DMA method, and the glass transition temperatures were determined. The deformation-strength properties and rigidity of polymer films were tested before and after light-thermal aging. Oxal was shown to reveal a fairly low viscosity and high gelation properties in relation to PVC. At the same time, its ability to reduce the glass transition temperature and elasticize the polymer in the glassy and rubbery state is somewhat lower than that of phthalate plasticizers. PVC samples plasticized with DBP have the highest resistance to light-thermal aging.
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