羰基硫醚
胺化
聚合物
哌嗪
电池(电)
锂(药物)
聚合
材料科学
化学
电化学
电极
化学工程
有机化学
功率(物理)
催化作用
物理化学
硫黄
内分泌学
工程类
物理
医学
量子力学
作者
Caiting Li,Xi Liu,Zhiling He,Tao Wang,Yuyuan Zhang,Yangfan Zhang,Yongtang Jia,Hui Yu,Qingguang Zeng,Da Wang,John H. Xin,Chunhui Duan,Fei Huang
标识
DOI:10.1016/j.jpowsour.2021.230464
摘要
Carbonyl polymers, such as poly(anthraquinonyl sulfide) (PAQS) and poly(benzoquinonyl sulfide) (PBQS), are typically selected as cathode materials for lithium-organic batteries (LOBs) because of their inherent high theoretical capacity and low solubility in the electrolyte. However, their commercialization is hindered by their relatively complex synthesis routes, low yields, and high cost. Herein, a carbonyl polymer poly(piperazine-alt-benzoquinone) (NP2), obtained from the polymerization of vanillin and piperazine with oxidative amination at the theoretical production cost of US $0.48 per gram, exhibits a high reversible capacity of 257 mAh g−1, leading to a cost performance of US $0.19 per 100 mAh, which is superior to the reported carbonyl polymers. Furthermore, ex situ X-ray photoelectron spectroscopy and ex situ and in situ Fourier-transform infrared measurements release the reversible electrochemical reaction mechanism of NP2 based on carbonyl redox chemistry. This study demonstrates a simple and effective strategy to synthesize low-cost carbonyl polymers, which will pave the way for their future application in high-performance LOBs.
科研通智能强力驱动
Strongly Powered by AbleSci AI