The 2:1 cocrystal of benzamide and pentafluorobenzoic acid

The crystal structure of the title compound, benzamide–2,3,4,5,6-penta­fluoro­benzoic acid (2/1), 2C7H7NO·C7HF5O2, consists of centrosymmetric hexa­meric supermolecules composed of four amide and two carboxylic acid mol­ecules connected via O—H⋯O and N—H⋯O hydrogen bonds. No phen­yl–perfluoro­phenyl π–π stacking inter­actions are observed in this cocrystal.