限制
比热
离子
单斜晶系
材料科学
德拜模型
熵(时间箭头)
热力学
物理
化学
结晶学
晶体结构
量子力学
机械工程
工程类
作者
Robert W. Hill,J. Cosier,D.A. Hukin
标识
DOI:10.1088/0022-3719/16/15/008
摘要
Specific heat measurements on monoclinic Gd2O3 show a cooperative peak at 3.8K. The entropy associated with this peak is the full 2R ln 8 expected for the Gd3+ ions. Measurements on GdAg are affected by the presence of small inclusions of Gd2O3, but it proves possible to allow for these and to deduce values for the electronic specific heat constant gamma which is 11.4+or-1.7 mJ mol.-1 K-2. For LaAg, gamma =9.9+or-0.2 mJ mol.-1 K-2. The lattice heat capacities are analysed in terms of a Debye temperature which is found to vary strongly with temperature; the low-temperature limiting values are 208K and 150K for GdAg and LaAg respectively.
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