材料科学
锡
氮化钛
分离器(采油)
电化学
化学工程
阴极
溶解
电导率
储能
钛
氮化物
硫黄
冶金
纳米技术
电极
化学
图层(电子)
功率(物理)
物理化学
工程类
物理
热力学
量子力学
作者
Xuan He,Yi Shuai,Li Na,Kanghua Chen,Youqiang Zhang,Zeping Zhang,Fuxing Gan
标识
DOI:10.1016/j.matlet.2017.12.069
摘要
Rechargeable lithium-sulfur (Li-S) batteries are considered as one of the most potential energy storage devices owing to their high theoretical capacity, environmental friendliness and low cost. However, the practical applications of Li-S batteries are restricted by the low conductivity of sulfur, serious dissolution of intermediate polysulfides and fast capacity degradation. Herein, we design a titanium nitride (TiN) modified separator to improve the long-term cycle stability and discharge capacity of Li-S batteries. Strong interaction between the TiN particles and polysulfides can greatly restrain the “shuttle effect” and benefit the cycle stability. With this modified separator, cathodes with a sulfur loading of 78.1% could deliver a high initial discharge capacity of 1296 mAh/g and demonstrate a decay rate of 0.17% per cycle under a high current density of 0.5C. Such superior electrochemical performances ascribe to the high conductivity of TiN and strong affinity between TiN particles and polysulfides.
科研通智能强力驱动
Strongly Powered by AbleSci AI