2D IR Spectroscopy of Hydrogen Bond Switching in Liquid Water
作者
Joseph J. Loparo,Sean T. Roberts,Andrei Tokmakoff
标识
DOI:10.1364/up.2006.me1
摘要
We use multidimensional infrared spectroscopy to observe the interconversion of hydrogen bonding environments in water. Our experiments show that hydrogen bond switching is concerted with broken hydrogen bonds disappearing on the timescale of intermolecular motions.