电解质
二进制数
极限(数学)
电荷(物理)
热力学
代数表达式
代数数
表达式(计算机科学)
代数方程
物理
统计物理学
化学
数学
数学分析
量子力学
程序设计语言
算术
非线性系统
计算机科学
电极
标识
DOI:10.1080/00268977500103051
摘要
Abstract The mean spherical approximation for the primitive model of electrolytic solutions is solved for the most general case of an arbitrary charge and size. It is found that the excess thermodynamic properties are scaled to the charge and the size by means of a rational expression involving a single parameter. This parameter is found by solving an algebraic equation. The explicit form of this equation is obtained for the cases of a binary mixture and in the limit of low concentrations.
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