芳基
键裂
过渡金属
化学
衍生化
功能群
组合化学
劈理(地质)
材料科学
有机化学
催化作用
烷基
高效液相色谱法
聚合物
断裂(地质)
复合材料
作者
Chenchen Li,Qi Qin,Aocong Guan,Wen Yang,Wanxiang Zhao
标识
DOI:10.1021/acs.joc.3c00370
摘要
We describe a general and efficient transition-metal free C-C bond cross-coupling of (hetero)aryl ethers and diarylmethanes via C(sp2)-O bond cleavage. The coupling reactions mediated by KHMDS proceeded well with high efficiency, broad substrate scope, and good functional group tolerance. The robustness and practicability of this protocol also have been demonstrated by easy gram-scale preparation and diversified product derivatization.
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