分子内力
接受者
化学
荧光
有机发光二极管
对映体
分子
光化学
共发射极
量子效率
结晶学
材料科学
立体化学
有机化学
光电子学
图层(电子)
凝聚态物理
量子力学
物理
作者
Xiangyu Dong,Shaogang Shen,Yuanyuan Qin,Xiaoxiao Hu,Hongjun Gao,Guanhao Liu,Teng Gao,Zhi Pang,Pengfei Wang,Ying Wang
标识
DOI:10.1016/j.cclet.2023.108311
摘要
The currently reported axial chiral molecules based on the 3,3′-substitution of the binaphthyl skeleton are limited by intrinsic fluorescence properties, resulting in generally low device efficiencies (EQE < 5%) of related organic light emitting diodes (OLEDs). Herein, we designed and synthesized four pair of chiral binaphthyl enantiomers (R/S-1 − R/S-4) adopting acceptor-donor-donor-acceptor (ADDA) structure by introducing different thioxanthone modification groups on the 3,3′-position of 2,2′-dimethoxy-1,1′-binaphthalene. Among them, emitter R/S-2 and R/S-4 obtained by enhancing intramolecular charge transfer exhibited TADF characteristics due to relatively small ΔEST of 0.12 eV and 0.17 eV, and relatively moderate SOC matrix elements of 0.28 cm−1 and 0.10 cm−1 between the 1CT and 3LE states. The CD spectra of these enantiomers in diluted solutions showed perfect mirror images and reasonable gabs for small organic molecules (10−4–10−3). And the external quantum efficiencies (EQE) of 10.9% and 8.32% for device A and B based on emitter S-2 and S-4 were highest compared with currently reported axial chiral molecules based on the 3,3′-position substitution of binaphthyl skeleton, providing simple molecular design strategies to construct efficient CP-OLED device.
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