Dynamical renormalization of electron-phonon coupling in conventional superconductors

The adiabatic Born-Oppenheimer approximation is considered to be a robust approach that very rarely breaks down. Consequently, it is predominantly utilized to address various electron-phonon properties in condensed matter physics. By combining many-body perturbation and density functional theories we demonstrate the importance of dynamical (nonadiabatic) effects in estimating superconducting properties in various bulk and two-dimensional materials. Apart from the expected long-wavelength nonadiabatic effects, we found sizable nonadiabatic Kohn anomalies away from the Brillouin zone center for materials with strong intervalley electron-phonon scatterings. Compared to the adiabatic result, these dynamical phonon anomalies can significantly modify electron-phonon coupling strength $\ensuremath{\lambda}$ and superconducting transition temperature ${T}_{c}$. Further, the dynamically induced modifications of $\ensuremath{\lambda}$ have a strong impact on transport properties, where probably the most interesting is the rescaling of the low-temperature and low-frequency regime of the scattering time $1/\ensuremath{\tau}$ from about ${T}^{3}$ to about ${T}^{2}$, resembling the Fermi liquid result for electron-electron scattering. Our goal is to point out the potential implications of these nonadiabatic effects and reestablish their pivotal role in computational estimations of electron-phonon properties.