Nanostructure engineering for ferroelectric photovoltaics

Ferroelectric photovoltaics have attracted increasing attention since their discovery in the 1970s, due to their above-bandgap photovoltage and polarized-light-dependent photocurrent. However, their practical applications have been limited by their weak visible light absorption and low photoconductivity. Intrinsic modification of the material, such as bandgap tuning through chemical doping, has proven effective, but usually leads to the degradation of ferroelectricity. Recently, various nanostructures, such as multilayer heterojunctions, nanoparticles, vertically aligned nanocomposites and polar nanoregions, have been developed to enhance photovoltaic performance. These approaches enable the nanoassembly of materials in a lower-dimension manner to optimize the bulk photovoltaic effect whilst effectively preserving or even inducing ferroelectricity. This review highlights the fabrication processes of these emerging ferroelectric nanostructures and evaluates their photovoltaic performance.