Efficient H2O2 Synthesis through a Two‐Electron Oxygen Reduction Reaction by Electrocatalysts

Abstract The two‐electron oxygen reduction reaction (2e‐ORR) for the sustainable synthesis of hydrogen peroxide (H 2 O 2 ) has demonstrated considerable potential for local production of this environmentally friendly chemical oxidant on small, medium, and large scales. This method offers a promising alternative to the energy‐intensive anthraquinone approach, placing a primary emphasis on the development of efficient electrocatalysts. Improving the efficiency of electrocatalysts and uncovering their catalytic mechanisms are essential steps in achieving high 2e‐ORR activity, selectivity, and stability. This comprehensive review summarizes recent advancements in electrocatalysts for in‐situ H 2 O 2 production, providing a detailed overview of the field. In particular, the review delves into the design, fabrication, and investigation of catalytic active sites contributing to H 2 O 2 selectivity. Additionally, it highlights a range of electrocatalysts including pure metals and alloys, transition metal compounds, single‐atom catalysts, and carbon‐based catalysts for the 2e‐ORR pathway. Finally, the review addresses significant challenges and opportunities for efficient H 2 O 2 electrosynthesis, as well as potential future research directions.