Fabrication of Ag-doped BiOF-reduced graphene oxide composites for photocatalytic elimination of organic dyes

Bismuth oxyfluoride (BiOF) is an emerging class of material with notable chemical stability, unique layered structure and striking energy band structure. Bi-based semiconductor materials and reduced graphene oxides (rGOs) have attracted considerable attention due to their broad spectrum of potential applications. Herein, we successfully synthesised an efficient photocatalyst comprising BiOF-rGO nanocomposites with embedded Ag nanoparticles using a simple hydrothermal method. The synthesised nanocomposites were characterised through Fourier-transform infrared spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy and ultraviolet (UV)-visible spectroscopy. The XRD results indicated the crystalline structures of the BiOF, Ag-doped BiOF and Ag-doped BiOF-rGO composites. Photocatalytic activity assessments focused on the degradation of methylene blue (MB) and methyl orange (MO) dyes under UV-light and sunlight irradiation. The Ag-doped BiOF-rGO composite exhibited significantly enhanced degradation efficiency, achieving 61.81 % and 74.25 % degradation of MB and MO, respectively, after 300 min under UV-light irradiation. On the contrary, pure BiOF demonstrated only 17.63 % and 48.29 % degradation for MB and MO, respectively, under similar conditions. Furthermore, under sunlight irradiation, the Ag-doped BiOF-rGO composite exhibited an MB removal efficiency of 43.87 % after 300 min, whereas pure BiOF showed only 27.47 % under identical conditions. These results underscore the potential of Ag-doped BiOF-rGO composites as highly efficient and adaptable photocatalysts for the photodegradation of organic dyes in industrial wastewater.