V‐Doping Strategy Induces the Construction of the CoFe‐LDHs/NF Electrodes with Higher Conductivity to Achieve Higher Energy Density for Advanced Energy Storage Devices

Abstract Doping of metal ions shows promising potential in optimizing and modulating the electrical conductivity of layered double hydroxides (LDHs). However, there is still much room for improvement in common metal ions and conventional doping methods. In contrast to previous methodologies, a hollow triangular nanoflower structure of CoFeV‐LDHs is devised, which is enriched with a greater number of oxygen vacancies. This resulted in a significant enhancement in the conductivity of the LDHs, leading to an increase in energy density following the appropriate doping of V. To investigate the impact of V‐doping on the energy density of the LDHs, in situ XPS and in situ X‐ray spectroscopy is employed. Regarding electrochemical performance, the CoFeV‐LDHs/NF electrode with optimal doping ratio exhibited a specific capacitance of 881 F g −1 at a current density of 1 A g −1 . The capacitance remained at 90.53% after 3000 cycles. In addition, the constructed battery‐type supercapacitor CoFeV‐LDHs/NF‐2//AC exhibited an impressive energy density of 124.7 Wh kg −1 at a power density of 850 W kg −1 and capacitance remained almost unchanged at 95.2% after 3000 cycles. All the above demonstrates the great potential of V‐doped LDHs and brings a new way for the subsequent research of LDHs.